On August 9, 2021, Stanley, Philip M.; Haimerl, Johanna; Thomas, Christopher; Urstoeger, Alexander; Schuster, Michael; Shustova, Natalia B.; Casini, Angela; Rieger, Bernhard; Warnan, Julien; Fischer, Roland A. published an article.Category: esters-buliding-blocks The title of the article was Host-guest interactions in metal-organic framework isoreticular series for molecular photocatalytic CO2 reduction. And the article contained the following:
A strategy to improve homogeneous mol. catalyst stability, efficiency, and selectivity is the immobilization on supporting surfaces or within host matrixes. Herein, we examine the co-immobilization of a CO2 reduction catalyst [ReBr(CO)3(4,4′-dcbpy)] and a photosensitizer [Ru(bpy)2(5,5′-dcbpy)]Cl2 using the isoreticular series of metal-organic frameworks (MOFs) UiO-66, -67, and -68. Specific host pore size choice enables distinct catalyst and photosensitizer spatial location-either at the outer MOF particle surface or inside the MOF cavities-affecting catalyst stability, electronic communication between reaction center and photosensitizer, and consequently the apparent catalytic rates. These results allow for a rational understanding of an optimized supramol. layout of catalyst, photosensitizer, and host matrix. The experimental process involved the reaction of Dimethyl 2′-amino-[1,1′:4′,1”-terphenyl]-4,4”-dicarboxylate(cas: 1312703-30-2).Category: esters-buliding-blocks
The Article related to metal organic framework photosensitizer photocatalytic carbon dioxide reduction, host-guest systems, hybrid materials, metal-organic frameworks, molecular catalysis, solar fuel production and other aspects.Category: esters-buliding-blocks
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics