Nassar, Youssef; Piva, Olivier published an article in 2021, the title of the article was Photoredox-catalyzed hydroxymethylation of β-ketoesters: application to the synthesis of [3.3.3] propellane lactones.Application of 10472-24-9 And the article contains the following content:
Photoredox-catalyzed hydroxymethylation of β-ketoesters substituted by an allyl subunit on the α-position afforded directly the corresponding bicyclic lactones possessing both a hydroxy group and an unsaturation A subsequent regioselective iodoetherification led to the formation of original [3.3.3] propellane structures. Substitution of the iodine atom by various nucleophiles afforded highly functionnalized structures including triazolomethyl derivatives The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).Application of 10472-24-9
The Article related to ketoester diastereoselective hydroxymethylation, bicyclic lactone preparation iodoetherification, propellane lactone preparation, triazolomethyl propellane lactone preparation click chem and other aspects.Application of 10472-24-9
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics