Shang, Wenbin; Zhu, Chunyu; Peng, Fengyuan; Pan, Zhiqiang; Ding, Yuzhen; Xia, Chengfeng published the artcile< Nitrogen-Centered Radical-Mediated Cascade Amidoglycosylation of Glycals>, Quality Control of 4098-06-0, the main research area is aminodeoxyglycoside aminoglycoside disaccharide TEMPO catalyst cascade stereoselective amidoglycosylation.
A nitrogen-centered radical-mediated strategy for preparing 1,2-trans-2-amino-2-deoxyglycosides in one step was established. The cascade amidoglycosylation was initiated by a benzenesulfonimide radical generated from NFSI under the catalytic reduction of TEMPO. The benzenesulfonimide radical was electrophilically added to the glycals, and then the resulting glycosidic radical was converted to oxocarbenium upon oxidation by TEMPO+, which enabled the following anomeric specific glycosylation.
Organic Letters published new progress about Aminoglycosides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 4098-06-0 belongs to class esters-buliding-blocks, and the molecular formula is C12H16O7, Quality Control of 4098-06-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics