Garcia-Gallego, Sandra; Andren, Oliver C. J.; Malkoch, Michael published the artcile< Accelerated Chemoselective Reactions to Sequence-Controlled Heterolayered Dendrimers>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is sequence controlled heterolayered dendrimer synthesis chemoselective reaction.
Chemoselective reactions are a highly desirable approach to generate well-defined functional macromols. Their extraordinary efficiency and selectivity enable the development of flawless structures, such as dendrimers, with unprecedented structure-to-property capacity but with typically tedious synthetic protocols. Here we demonstrate the potency of chemoselective reactions to accomplish sequence-controlled heterolayered dendrimers. An accurate accelerated design of bis-MPA monomers with orthogonally complementary moieties and a wisely selected chem. toolbox generated highly complex monodisperse dendrimers through simplified protocols. The versatility of the strategy was proved by obtaining different dendritic families with different properties after altering the order of addition of the monomers. Moreover, we evaluated the feasibility of the one-pot approach toward these heterolayered dendrimers as proof-of-concept.
Journal of the American Chemical Society published new progress about 1,3-Dipolar cycloaddition reaction (CuAAC). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics