Zuo, Xiang; Cheng, Cang; Zhang, Yanghui published the artcile< Palladium-catalyzed cross-coupling of 2-iodobiphenyls with ortho-chloroacetophenones through dual C-H arylation for the construction of tribenzo[a,c,f]cyclooctanones>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is tribenzocyclooctanone preparation; iodobiphenyl ortho chloroacetophenone cross coupling reaction palladium arylation.
The palladium-catalyzed cross-coupling reaction of 2-iodobiphenyls with ortho-chloroacetophenones has been developed. The reaction involves C-H activation of 2-iodobiphenyls and yields eight-membered carbocycles by forming two C-C bonds. The protocol provides a straightforward method for the construction of tribenzo[a,c,f]cyclooctanones with simple substrates and allows easy access to its various derivatives
Organic Chemistry Frontiers published new progress about Acetophenones Role: RCT (Reactant), RACT (Reactant or Reagent) (ortho-chloro-). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
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