Suzuki, Shuichi; Nagata, Atsuki; Kuratsu, Masato; Kozaki, Masatoshi; Tanaka, Rika; Shiomi, Daisuke; Sugisaki, Kenji; Toyota, Kazuo; Sato, Kazunobu; Takui, Takeji; Okada, Keiji published the artcile< Trinitroxide-Trioxytriphenylamine: Spin-State Conversion from Triradical Doublet to Diradical Cation Triplet by Oxidative Modulation of a π-Conjugated System>, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is trinitroxide trioxytriphenylamine oxidation triradical doublet diradical cation triplet.
Herein, we report an oxidative spin-state conversion from a triradical doublet ground state trinitroxide substituted trioxytriphenylamine (6) (I) to diradical cation triplet ground states (6+) (II). We also determined the crystal structures of 6 and 6+. The spin properties of these compounds were extensively clarified with theor. analyses of zero-field splitting and g tensors.
Angewandte Chemie, International Edition published new progress about Antiferromagnetic exchange. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics