Njeri, Dancan K.; Pertuit, Claude J.; Ragains, Justin R. published the artcile< 1,2-cis-Selective glucosylation enabled by halogenated benzyl protecting groups>, Name: Benzyl (3-hydroxypropyl)carbamate, the main research area is disaccharide thioglycoside stereoselective glycosylation preparation uronate cholesterol; Williamson etherification stereoselective glycosylation protecting group glucosylation thioglucoside trichloroacetimidate.
We report on our initial results from a systematic effort to implement electron-withdrawing protecting groups and Lewis basic solvents/additives as an approach to 1,2-cis(α)-selective O-glucosylation. 1,2-cis-Selective O-glucosylation are reported with thioglucosides and glucosyl trichloroacetimidates and a range of acceptors. A correlation between electron-withdrawing effects and 1,2-cis selectivity has been established. This phenomenon may prove to be broadly applicable in the area of chem. O-glycosylation.
Organic & Biomolecular Chemistry published new progress about Disaccharides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 34637-22-4 belongs to class esters-buliding-blocks, and the molecular formula is C11H15NO3, Name: Benzyl (3-hydroxypropyl)carbamate.
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