Ulrich, Sebastian; Sadeghpour, Amin; Rossi, Rene M.; Bruns, Nico; Boesel, Luciano F. published the artcile< Wide Range of Functionalized Poly(N-alkyl acrylamide)-Based Amphiphilic Polymer Conetworks via Active Ester Precursors>, SDS of cas: 71195-85-2, the main research area is polyalkylacrylamide amphiphilic polymer network ester precursor.
A versatile strategy for the fabrication of functional poly(N-alkyl acrylamide)-based amphiphilic polymer conetworks (APCNs) from hydrophobic precursor networks is presented. Herein, the active ester monomer pentafluorophenyl acrylate (PFPA) acts as a general hydrophobic masking group for N-alkyl acrylamides. Amidation reactions with different amines allow the transformation of one PFPA-based hydrophobic precursor network into a multitude of different APCNs that possess optical transparency and nanophase-separated morphologies. Accordingly, the properties of these ACPNs can be tailored to the desired application by simple variation of the amide functionality. Furthermore, combination of PFPA with another hydrophobically masked monomer allows for the functionalization of the hydrophilic phase of APCNs in precisely defined amounts Controlled integration of pendant groups such as pH-responsive imidazole, fluorescent dyes, and biotin for specific protein binding is achieved, greatly expanding the functionality of the APCNs. Such functionalized APCNs could find application as stimuli-responsive drug delivery membranes, smart hydrogels, biosensors, or as matrixes for biocatalysis.
Macromolecules (Washington, DC, United States) published new progress about Amidation. 71195-85-2 belongs to class esters-buliding-blocks, and the molecular formula is C9H3F5O2, SDS of cas: 71195-85-2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics