Li, Yan; Wu, Weibo; Li, Hu; Zhao, Wenfeng; Yang, Song published the artcile< Sustainable and rapid production of biofuel γ-valerolactone from biomass-derived levulinate enabled by a fluoride-ionic liquid>, Related Products of 112-63-0, the main research area is biofuel valerolactone biomass derived levulinate fluoride ionic liquid.
γ-Valerolactone (GVL) is a versatile biomass-derived mol. for both value-added chems. and biofuels, which is typically prepared from levulinates over metal particles or oxides in the presence of hydrogen, formic acid or alc. Herein, we reported a rapid and mild approach for cascade hydrogenation-cyclization of Et levulinate (EL) to GVL in the presence of readily available ionic liquid tetrabutylammonium fluoride ([TBA]F) and polymethylhydrosiloxane (PMHS) as catalyst and hydrogen source, resp. After reacting at room temperature for 30 min, a high GVL yield of 85% with TOF value of 52 h-1 could be obtained over 3 mol% [TBA]F. In addition to optimizing reaction parameters, the catalytic mechanism was also elucidated for the one-pot sequential transformation of EL to GVL.
Energy Sources, Part A: Recovery, Utilization, and Environmental Effects published new progress about Biofuels. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Related Products of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics