Shahabuddin, Mohammad; Akutsu, Akira; Kimura, Takao; Karikomi, Michinori published the artcile< Synthesis of Helical Quinone Derivatives by Oxidative Coupling of Substituted 2-Hydroxybenzo[c]phenanthrenes>, Product Details of C19H34O2, the main research area is crystal mol structure bibenzo phenanthrylidene dione; hydroxybenzo phenanthrene electrocyclization oxidative aromatization coupling; helical quinone preparation electrocyclization oxidative aromatization coupling.
A concise synthesis of novel substituted quinone derivatives from com. available starting materials was developed. For this synthesis, classical photo-induced 6π-electrocyclization was utilized, followed by oxidative aromatization reaction, and subsequent oxidative coupling reactions in the presence of CuCl(OH)-TMEDA. The unique quinone derivatives were characterized by IR, 1H, and 13C NMR spectroscopies, and mass spectroscopic data anal. In some cases, the keto dimers were obtained as significant intermediates for the quinone synthesis.
Synthesis published new progress about Aromatization. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Product Details of C19H34O2.
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