Nagy, Audric; Collard, Laurent; Indukuri, Kiran; Leyssens, Tom; Riant, Olivier published the artcile< Enantio-, Regio- and Chemoselective Copper-Catalyzed 1,2-Hydroborylation of Acylsilanes>, Computed Properties of 112-63-0, the main research area is hydroboration reduction ketone acylsilane preparation hydroxyalkylsilane enantiomer copper catalyst; copper diphosphine complex catalyst asym hydroboration acylsilane preparation hydroxyalkylsilane; chiral alc preparation hydroxyalkylsilane asym reduction ketone acylsilane pinacolboronate; acylsilane; asymmetric synthesis; copper; hydroborylation; hydroxysilanes.
Enantioselective synthesis of synthetically significant (α-hydroxyallyl)silanes, (α-hydroxybenzyl)silanes, and (α-hydroxyalkyl)silanes is reported. The present copper-catalyzed 1,2-selective hydroborylation of acylsilanes affords the aforementioned products in high yields and with high enantiomeric excesses. This robust and scalable additive-free catalytic system relies on the use of low copper(II) acetate and diphosphine ligand loadings at room temperature in the presence of a com. available and bench-stable hydride source.
Chemistry – A European Journal published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation) (silylated). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Computed Properties of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics