Boyington, Allyson J.; Riu, Martin-Louis Y.; Jui, Nathan T. published the artcile< Anti-Markovnikov Hydroarylation of Unactivated Olefins via Pyridyl Radical Intermediates>, Product Details of C19H34O2, the main research area is alkylpyridine preparation; halopyridine olefin regioselective hydroarylation iridium catalyst.
The intermol. alkylation of pyridine units with simple alkenes has been achieved via a photoredox radical mechanism. This process occurs with complete regiocontrol, where single-electron reduction of halogenated pyridines regiospecifically yields the corresponding radicals in a programmed fashion, and radical addition to alkene substrates occurs with exclusive anti-Markovnikov selectivity. This system is mild, tolerant of many functional groups, and effective for the preparation of a wide range of complex alkylpyridines.
Journal of the American Chemical Society published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Product Details of C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics