Taylor, Scott D.; Kotoris, Christopher C.; Dinaut, A. Nicole; Chen, Mei-Jin published the artcile< Synthesis of aryl(difluoromethylene phosphonates) via electrophilic fluorination of α-carbanions of benzylic phosphonates with N-fluorobenzenesulfonimide>, Reference of 112-63-0, the main research area is benzylic phosphonate carbanion electrophilic fluorination fluorobenzenesulfonimide.
The electrophilic fluorination of a wide variety of benzylic phosphonates with N-fluorobenzenesulfonimide was examined The fluorination reaction proceeds well in the presence of an array of functional groups such as nitro, bromo, ketone, ester, Ph and ether groups. Ph and biphenyl derivatives containing two α,α-difluoromethylenephosphonate groups can also be prepared This procedure is compatible with Me or Et phosphonate esters but not with t-Bu esters or with benzylic phosphonates containing an addnl. benzylic moiety at the para-position.
Tetrahedron published new progress about Carbanions Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Reference of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics