Hu, Ze Kai; Cui, Hai Lei; Jiang, Kun; Chen, Ying Chun published the artcile< Enantioselective O-allylic alkylation of Morita-Baylis-Hillman carbonates with oxime>, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is Baylis Hillman carbonate oxime enantioselective allylic alkylation quinuclidine catalyst; unsaturated carboxylate oxime ether asym synthesis.
The enantioselective O-allylic alkylation of acetophenone oxime with various Morita-Baylis-Hillman (MBH) carbonates was accomplished by the catalysis of a com. available cinchona alkaloid (DHQD)2PHAL. The corresponding O-allylic products were obtained in moderate to excellent yields up to 96% ee.
Science in China, Series B: Chemistry published new progress about Alkylation catalysts, stereoselective. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics