Calter, Michael A.; Phillips, Ryan M.; Flaschenriem, Christine published the artcile< Catalytic, Asymmetric, ""Interrupted"" Feist-Benary Reactions>, Formula: C19H34O2, the main research area is hydroxydihydrofuran preparation catalytic asym interrupted Feist Benary.
Pyrimidine derivatives of the cinchona alkaloids function as excellent asym. catalysts for the interrupted Feist-Benary reaction. This reaction produces highly substituted hydroxydihydrofurans from simple starting materials under mild conditions. The asym. reaction gives high enantioselectivities with unsubstituted bromoketones and high enantio- and diastereoselectivities with substituted substrates. Mechanistic experiments suggest that the hydrobromide salt of the alkaloid derivative is the active catalyst for the reaction.
Journal of the American Chemical Society published new progress about Condensation reaction. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Formula: C19H34O2.
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Ester – an overview | ScienceDirect Topics