Popa, Flavia; Lameiras, Pedro; Henon, Eric; Moldovan, Oana; Martinez, Agathe; Batiu, Carmen; Ramondenc, Yvan; Darabantu, Mircea published the artcile< Amino-s-triazines - Synthesis and stereochemistry of restricted rotational phenomena - First use of a C-2-substituted serinol in tandem with masked 4-piperidone for selective amination of cyanuric chloride>, Name: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is aminotriazine preparation restricted rotation; serinol piperidone amination cyanuric chloride.
Starting from 4-piperidone monohydrate hydrochloride (or the hydrochloride of its ethylene ketal) alone, otherwise in tandem with a C-2-substituted 2-aminopropane-1,3-diol (“”serinol””) as amino-nucleophiles in reaction with cyanuric chloride, the synthesis of novel N-substituted amino-s-triazines is reported. The stereochem. of rotational phenomena occurring about the newly created C(s-triazine)-N< (exocyclic) partial double bonds in the title compounds, seen as new dendritic building blocks, is discussed. Canadian Journal of Chemistry published new progress about Amination. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Name: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics