Iriarte, Igor; Vera, Silvia; Badiola, Eider; Mielgo, Antonia; Oiarbide, Mikel; Garcia, Jesus M.; Odriozola, Jose M.; Palomo, Claudio published the artcile< Asymmetric Assembly of All-Carbon Tertiary/Quaternary Nonadjacent Stereocenters through Organocatalytic Conjugate Addition of α-Cyanoacetates to a Methacrylate Equivalent>, Reference of 112-63-0, the main research area is organocatalytic conjugate addition cyanoacetate methacrylate equivalent; Brønsted bases; Michael reactions; asymmetric organocatalysis; quaternary stereocenters; stereoselective protonation.
An efficient, highly diastereo- and enantioselective assembly of acyclic carbonyl fragments possessing nonadjacent all-carbon tertiary/quaternary stereoarrays is reported based on a Bronsted base catalyzed Michael addition/α-protonation sequence involving α-cyanoacetates and 2,4-dimethyl-4-hydroxypenten-3-one as novel methacrylate equivalent
Chemistry – A European Journal published new progress about Carbonyl compounds (organic) Role: SPN (Synthetic Preparation), PREP (Preparation) (acyclic). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Reference of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics