Palo-Nieto, Carlos; Sau, Abhijit; Galan, M. Carmen published the artcile< Gold(I)-Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals>, Safety of (2R,3R,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate, the main research area is deoxyglycoside stereoselective synthesis gold catalyzed hydrofunctionalization glycal enol ether; oligosaccharide stereoselective synthesis gold catalyzed hydrofunctionalization glycal enol ether; glycosyl amino acid stereoselective synthesis gold catalyzed hydrofunctionalization glycal; glycoconjugate stereoselective synthesis gold catalyzed hydrofunctionalization glycal enol ether.
Au(I) in combination with AgOTf enables the unprecedented direct and æµ?stereoselective catalytic synthesis of deoxyglycosides from glycals. Mechanistic investigations suggest that the reaction proceeds via Au(I)-catalyzed hydrofunctionalization of the enol ether glycoside. The room temperature reaction is high yielding and amenable to a wide range of glycal donors and OH nucleophiles.
Journal of the American Chemical Society published new progress about Amino acids Role: SPN (Synthetic Preparation), PREP (Preparation) (glycosyl). 4098-06-0 belongs to class esters-buliding-blocks, and the molecular formula is C12H16O7, Safety of (2R,3R,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics