Gao, Mengyu; Sun, Deli; Gong, Hegui published the artcile< Ni-Catalyzed Reductive C-O Bond Arylation of Oxalates Derived from æµ?Hydroxy Esters with Aryl Halides>, Electric Literature of 617-55-0, the main research area is synthesis aryl ester reductive cross coupling oxalate aryl halide; aryl ester preparation arylation aryl halide oxalate radical fragmentation; oxalate radical fragmentation reduction potential.
A Ni-catalyzed reductive cross-coupling of æµ?hydroxycarbonyl compounds modified with oxalyl groups and aryl halides has been developed that furnishes æµ?aryl esters under mild conditions and tolerates a variety of functionalized aryl halides bearing electron-withdrawing and -donating groups. This work highlights C-O bond fragmentation on secondary alkyl carbon centers that generates æµ?carbonyl radicals.
Organic Letters published new progress about Aryl iodides Role: RCT (Reactant), RACT (Reactant or Reagent). 617-55-0 belongs to class esters-buliding-blocks, and the molecular formula is C6H10O5, Electric Literature of 617-55-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics