Cramer, David L.; Bera, Srikrishna; Studer, Armido published the artcile< Exploring Cooperative Effects in Oxidative NHC Catalysis: Regioselective Acylation of Carbohydrates>, Product Details of C19H34O2, the main research area is regioselective acylation oxidative esterification catalyst amino linked neodisaccharide preparation; N-heterocyclic carbene; carbohydrates; cooperative catalysis; organocatalysis; synthetic methods.
The utility of oxidative N-heterocyclic carbene (NHC) catalysis for both the regioselective and chemoselective functionalization of carbohydrates is explored. Chiral NHCs allow for the highly regioselective oxidative esterification of various carbohydrates using aldehydes as acylation precursors. The transformation was also shown to be amenable to both cis/trans diol isomers, free amino groups, and selective for specific sugar epimers in competition experiments Efficiency and regioselectivity of the acylation can be improved upon using two different NHC catalysts that act cooperatively. The potential of the method is documented by the regioselective acylation of an amino-linked neodisaccharide.
Chemistry – A European Journal published new progress about Acylation. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Product Details of C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics