Brito, Gilmar A.; Jung, Woo-Ok; Yoo, Minjin; Krische, Michael J. published the artcile< Enantioselective Iridium-Catalyzed Allylation of Acetylenic Ketones via 2-Propanol-Mediated Reductive Coupling of Allyl Acetate: C14-C23 of Pladienolide D>, SDS of cas: 112-63-0, the main research area is acetylenic ketone allylation enantioselective iridium catalyzed; pladienolide D fragment preparation enantioselective allylation; enantioselectivity; iridium; ketone allylation; transfer hydrogenation; é?allyl.
Highly enantioselective catalytic reductive coupling of allyl acetate with acetylenic ketones occurs in a chemoselective manner in the presence of aliphatic or aromatic ketones. This method was used to construct C14-C23 fragment (I) of pladienolide D in half the steps previously required.
Angewandte Chemie, International Edition published new progress about Alkynyl ketones Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, SDS of cas: 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics