Santschi, Nico; Matthey, Coraline; Schwenk, Rino; Otth, Elisabeth; Togni, Antonio published the artcile< On the Effect of Backbone Modifications in 3,3-Dimethyl-1-(trifluoromethyl)-3H-1ä½?,2-benziodaoxole>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is dimethyl trifluoromethyl benziodaoxole.
We report on the effect of small side-chain modifications to the structure of 3,3-dimethyl-1-(trifluoromethyl)-3H-1ä½?,2-benziodaoxole (1b) on its reactivity, as expressed by the initial rate v0 in a model reaction, and show how the latter can be successfully correlated to an easily determined phys. parameter p, a 13C NMR chem. shift. The relationship v0 é?p is already present in the simplest starting material devoid of the hypervalent bond and the iodine core and, therefore, presents an interesting approach towards the future scaffold-optimization of this class of reagents.
European Journal of Organic Chemistry published new progress about Crystal structure. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics