Lipshutz, Bruce H.; Frieman, Bryan A.; Unger, John B.; Nihan, Danielle M. published the artcile< Thermally accelerated asymmetric hydrosilylations using ligated copper hydride>, Application In Synthesis of 112-63-0, the main research area is thermally microwave accelerated asym hydrosilylation ligated copper hydride catalyst; prochiral substrate asym hydrosilylation ligated copper hydride catalyst.
Exposure of a variety of prochiral substrates to [(R)-(-)-DTBM-SEGPHOS]CuH + PMHS under microwave or conventionally heated conditions reduces reaction times for these hydrosilylations from hours to minutes without significant erosion in ee in most cases. Thus, microwave assisted hydrosilylation of isophorone with poly(methylhydrosiloxane) at 60æ?for 60 min gave 100% (R)-3,3,5-trimethylcyclohexanone.
Canadian Journal of Chemistry published new progress about Hydrosilylation catalysts, stereoselective. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Application In Synthesis of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics