Vijeta, Arjun; Casadevall, Carla; Roy, Souvik; Reisner, Erwin published the artcile< Visible-Light Promoted C-O Bond Formation with an Integrated Carbon Nitride-Nickel Heterogeneous Photocatalyst>, Reference of 112-63-0, the main research area is visible light carbon nitride nickel photocatalyst bond formation; carbon nitride; cross-coupling reaction; dual catalysis; heterogeneous catalysis; photocatalysis.
Ni-deposited mesoporous graphitic carbon nitride (Ni-mpg-CNx) is introduced as an inexpensive, robust, easily synthesizable and recyclable material that functions as an integrated dual photocatalytic system. This material overcomes the need of expensive photosensitizers, organic ligands and additives as well as limitations of catalyst deactivation in the existing photo/Ni dual catalytic cross-coupling reactions. The dual catalytic Ni-mpg-CNx is demonstrated for C-O coupling between aryl halides and aliphatic alcs. under mild condition. The reaction affords the ether product in good-to-excellent yields (60-92%) with broad substrate scope, including heteroaryl and aryl halides bearing electron-withdrawing, -donating and neutral groups. The heterogeneous Ni-mpg-CNx can be easily recovered from the reaction mixture and reused over multiple cycles without loss of activity. The findings highlight exciting opportunities for dual catalysis promoted by a fully heterogeneous system.
Angewandte Chemie, International Edition published new progress about Coupling reaction. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Reference of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics