Powers, David C.; Lee, Eunsung; Ariafard, Alireza; Sanford, Melanie S.; Yates, Brian F.; Canty, Allan J.; Ritter, Tobias published the artcile< Connecting binuclear Pd(III) and mononuclear Pd(IV) chemistry by Pd-Pd bond cleavage>, Related Products of 112-63-0, the main research area is oxidation palladium cyclometalated binuclear benzoquinoline complex mechanism; trifluoromethylation electrophilic palladium cyclometalated binuclear benzoquinoline complex.
Exptl. and theor. evaluation of oxidation of Pd(II) cyclometalated benzo[h]quinoline carboxylato-bridged binuclear complexes with trifluoromethylating electrophilic reagents is presented. Oxidation of binuclear Pd(II) μ-carboxylate complexes with PhICl2 or PhI(OAc)2 has previously been shown to afford binuclear Pd(III) complexes featuring a Pd-Pd bond. In contrast, oxidation of binuclear Pd(II) complexes with electrophilic trifluoromethylating (“”CF3+””) reagents has been reported to afford mononuclear Pd(IV) complexes. These studies suggest that a mononuclear Pd(IV) complex is generated by an oxidation-fragmentation sequence proceeding via fragmentation of an initially formed, formally binuclear Pd(III), intermediate. The observation that binuclear Pd(III) and mononuclear Pd(IV) complexes are accessible in the same reactions offers an opportunity for understanding the role of nuclearity in both oxidation and subsequent C-X bond-forming reactions.
Journal of the American Chemical Society published new progress about Aromatic nitrogen heterocycles Role: FMU (Formation, Unclassified), PEP (Physical, Engineering or Chemical Process), PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), FORM (Formation, Nonpreparative), PROC (Process), RACT (Reactant or Reagent), PREP (Preparation) (benzo[h]quinolines, palladium complexes). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Related Products of 112-63-0.
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