Nuriye, Ahmed Y.; Barr, Joseph published the artcile< Iodine-promoted oxidative homocoupling of methyl 2-arylacetates under equilibrium conditions using potassium tert-butoxide as a base>, Computed Properties of 30095-98-8, the main research area is phenylacetate iodine potassium tert butoxide promoter diastereoselective oxidative homocoupling; diphenylsuccinate preparation.
Iodine-promoted dimerization of enolates of Me 2-phenylacetates generated with t-BuOK under equilibrium conditions were reported. The oxidative homocoupling reaction furnished a mixture of dl and meso dimers in moderate to good yields and diastereoselectivity. Electron-withdrawing substituents on the Ph ring seem to facilitate dimerization leading to higher yields and ortho-substituted Ph acetates afford better diastereoselectivity.
Results in Chemistry published new progress about Aromatic esters Role: RCT (Reactant), RACT (Reactant or Reagent). 30095-98-8 belongs to class esters-buliding-blocks, and the molecular formula is C9H9NO4, Computed Properties of 30095-98-8.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics