Meng, Shuai; Zhong, Wenhe; Yao, Wang; Li, Zhongjun published the artcile< Stereoselective Phenylseleno-glycosylation of Glycals Bearing a Fused Carbonate Moiety toward the Synthesis of 2-Deoxy-β-galactosides and β-Mannosides>, Product Details of C12H16O7, the main research area is selenide phenyliodine fluoroacetate phenylseleno glycosylation glycoside preparation; stereoselective glycosylation glycal fused carbonate synthesis deoxygalactoside mannoside glycoside.
A phenylseleno-glycosylation reaction of glycal derivatives mediated by di-Ph diselenide and phenyliodine(III) bis(trifluoroacetate) under mild conditions is described. Stereoselective glycosylation has been achieved by installing fused carbonate on those glycals. 3,4-O-carbonate galactals and 2,3-O-carbonate 2-hydroxyglucals are converted into corresponding glycosides in good yields with excellent β-selectivity, resulting in 2-phenylseleno-2-deoxy-β-galactosides and 2-phenylseleno-β-mannosides which are good precursors of 2-deoxy-β-galactosides and β-mannosides, resp.
Organic Letters published new progress about Glycals Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 4098-06-0 belongs to class esters-buliding-blocks, and the molecular formula is C12H16O7, Product Details of C12H16O7.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics