《Regioselective Intramolecular Allene Amidation Enabled by an EDA Complex》 was written by Liu, Lu; Ward, Robert M.; Schomaker, Jennifer M.. Name: N-tert-Butoxycarbonylhydroxylamine And the article was included in Chemistry – A European Journal in 2020. The article conveys some information:
A direct and regioselective addition of amidyl radicals to allenes to furnish highly modifiable heterocycle scaffolds such as I that can serve as scaffolds for drugs and natural products was developed. Various substitution patterns were well-tolerated and diverse electrophiles could be used to trap the intermediate vinyl radicals. Ongoing investigations are targeted toward methods that deliver products where all three allene carbons were functionalized, as well as exptl. and computational studies of other radical additions to allenes to achieve complexity-forming cascade reactions. The experimental part of the paper was very detailed, including the reaction process of N-tert-Butoxycarbonylhydroxylamine(cas: 36016-38-3Name: N-tert-Butoxycarbonylhydroxylamine)
N-tert-Butoxycarbonylhydroxylamine(cas: 36016-38-3) belongs to anime. Amines can be classified according to the nature and number of substituents on nitrogen. Aliphatic amines contain only H and alkyl substituents. Aromatic amines have the nitrogen atom connected to an aromatic ring.Important amines include amino acids, biogenic amines, trimethylamine, and aniline. Inorganic derivatives of ammonia are also called amines, such as monochloramine (NClH2).Name: N-tert-Butoxycarbonylhydroxylamine
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics