In 2021,Organic Chemistry Frontiers included an article by Liu, Chengwei; Szostak, Michal. Recommanded Product: 1877-71-0. The article was titled 《Decarbonylative sulfide synthesis from carboxylic acids and thioesters via cross-over C-S activation and acyl capture》. The information in the text is summarized as follows:
A method for the synthesis of sulfides from carboxylic acids via thioester C-S activation and acyl capture has been developed, wherein thioesters serve as dual electrophilic activators of carboxylic acids and S-nucleophiles through the merger of decarbonylative palladium catalysis and sulfur coupling. This new concept employs readily available carboxylic acids as coupling partners to directly intercept sulfur reagents via redox-neutral thioester-enabled cross-over thioetherification. The scope of this platform is demonstrated in the highly selective decarbonylative thioetherification of a variety of carboxylic acids and thioesters, including late-stage derivatization of pharmaceuticals and natural products. This method operates under mild, external base-free, and operationally practical conditions, providing a powerful new framework to unlock aryl electrophiles from carboxylic acids and increase the reactivity by employing common building blocks in organic synthesis.3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0Recommanded Product: 1877-71-0) was used in this study.
3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0) belongs to esters. Esters are more polar than ethers but less polar than alcohols. Recommanded Product: 1877-71-0 They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics