Lee, Jung Gyu; Choi, Kyung Il; Pae, Ae Nim; Koh, Hun Yeong; Kang, Yonghan; Cho, Yong Seo published the artcile< Indium-mediated diastereoselective allylation reactions: preparation of α-hydroxy and α-amino acids>, Synthetic Route of 112-63-0, the main research area is indium asym allylation glyoxyloylbornane sultam hemiacetal imine.
Stereoisomers of N-glyoxyloylbornane-10,2-sultam hemiacetal I and related imine II reacted with allyl iodide in the presence of indium in DMF to give the corresponding α-hydroxy and α-amino camphor sultam derivatives with high diastereoselectivities (86-90% de). This method could be useful for the preparation of α-hydroxy and α-amino acids.
Journal of the Chemical Society, Perkin Transactions 1 published new progress about Allylation, stereoselective. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Synthetic Route of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics