In 2019,Chemical Science included an article by D’Amato, Erica M.; Borgel, Jonas; Ritter, Tobias. Name: N-tert-Butoxycarbonylhydroxylamine. The article was titled 《Aromatic C-H amination in hexafluoroisopropanol》. The information in the text is summarized as follows:
A direct radical aromatic amination reaction that provides unprotected anilines e.g., 3-O2NC6H4NH2 with an improvement in the substrate scope compared to prior art have been reported. Hydrogen bonding by the solvent hexafluoroisopropanol to anions of cationic species is responsible for increased reactivity and can rationalize the enhancement in substrate scope. These findings may have bearings on radical additions to arenes e.g., nitrobenzene for direct C-H functionalization in general. In the experiment, the researchers used many compounds, for example, N-tert-Butoxycarbonylhydroxylamine(cas: 36016-38-3Name: N-tert-Butoxycarbonylhydroxylamine)
N-tert-Butoxycarbonylhydroxylamine(cas: 36016-38-3) belongs to anime. Aniline, ethanolamines, and several other amines are major industrial commodities used in making rubber, dyes, pharmaceuticals, and synthetic resins and fibres and for a host of other applications. Most of the numerous methods for the preparation of amines may be broadly divided into two groups: (1) chemical reduction (replacement of oxygen with hydrogen atoms in the molecule) of members of several other classes of organic nitrogen compounds and (2) reactions of ammonia or amines with organic compounds.Name: N-tert-Butoxycarbonylhydroxylamine
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