《Metal-free iminyl radical-mediated C-C single bond cleavage/functionalization of redox-active oxime esters》 was published in Organic Chemistry Frontiers in 2020. These research results belong to Zhang, Miao-Miao; Li, Shi-Hong; Tu, Jia-Lin; Min, Qing-Qiang; Liu, Feng. Application In Synthesis of Benzyl acrylate The article mentions the following:
A visible-light-driven iminyl radical-mediated C-C bond cleavage and functionalization of cycloketone oxime esters have been accomplished to give distal cyano pyridines such as I [R1 = H, Me, Bn, etc.; R2 = H, Me, Ph, etc.; R3 = H, 4-Me, 5-Me; R4 = H, Ph, 4-ClC6H4; R5 = H, 4-MeC6H4; n = 1, 2, 3, etc.; X = O, CH(Ph), CH(OBn), etc.] and distal cyano alkenes such as II [R6 = COOEt, Ph, 2-naphthyl, etc.; R7 = H, Me, Bn, etc.; R8 = H, Me, Ph, etc.]. This protocol is simple and does not require expensive and toxic photoredox and/or transition-metal catalysis, providing a novel catalyst-free strategy for alkylation, allylation, vinylation and alkynylation through addition of C(sp3)-centered radicals to various unsaturated acceptors. The com. available and photoactive Hantzsch ester effectively serves as an electron donor, as well as a hydrogen atom source. In the experiment, the researchers used Benzyl acrylate(cas: 2495-35-4Application In Synthesis of Benzyl acrylate)
Benzyl acrylate(cas: 2495-35-4) has been used in preparation of high refractive index polyacrylates. Benzyl acrylate is used in the preparation of heptanoic acid benzyl ester. It is used to prepare polybenzylacrylate using azobisisobutyronitrile as initiator.Application In Synthesis of Benzyl acrylate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics