《Direct Construction of NOBINs via Domino Arylation and Sigmatropic Rearrangement Reactions》 was published in Chinese Journal of Chemistry in 2020. These research results belong to Zhang, Ji-Wei; Qi, Liang-Wen; Li, Shaoyu; Xiang, Shao-Hua; Tan, Bin. Name: N-tert-Butoxycarbonylhydroxylamine The article mentions the following:
Privileged 2-amino-2′-hydroxy-1,1′-binaphthyl (NOBIN) frameworks were constructed through a novel domino arylation of naphthylhydroxylamines with diarylhalonium salts and sigmatropic rearrangement in a transition metal-free fashion. This protocol bears broad substrate generality and proceeded under mild reaction conditions, affording diversified NOBINs in high efficiency with absolute regiocontrol during the rearrangement process. Optically active product was accessible by chiral N-heterocyclic carbene-catalyzed kinetic resolution in one pot or diastereoselective [3,3]-rearrangement guided by a removable chiral auxiliary. Remarkably, diarylchloronium and diarylbrominium salts were employed as arylation reagents for the first time in assembling such representative biaryl frameworks.N-tert-Butoxycarbonylhydroxylamine(cas: 36016-38-3Name: N-tert-Butoxycarbonylhydroxylamine) was used in this study.
N-tert-Butoxycarbonylhydroxylamine(cas: 36016-38-3) belongs to anime. Amine, any member of a family of nitrogen-containing organic compounds that is derived, either in principle or in practice, from ammonia (NH3). Naturally occurring amines include the alkaloids, which are present in certain plants; the catecholamine neurotransmitters (i.e., dopamine, epinephrine, and norepinephrine); and a local chemical mediator, histamine, that occurs in most animal tissues.Name: N-tert-Butoxycarbonylhydroxylamine
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