Wei, Dilan; Kodikara, Mahesh S.; Morshedi, Mahbod; Moxey, Graeme J.; Wang, Huan; Wang, Genmiao; Quintana, Cristobal; Zhang, Chi; Stranger, Rob; Cifuentes, Marie P.; Humphrey, Mark G. published the artcile< Syntheses and Optical Properties of Azo-Functionalized Ruthenium Alkynyl Complexes>, COA of Formula: C19H34O2, the main research area is azo functionalized ruthenium alkynyl complex preparation crystal mol structure; electrochem redox azo functionalized ruthenium alkynyl complex; alkene ligands; alkyne ligands; electrochemistry; nonlinear optics; transition metals.
The syntheses of trans-[Ru(CC-1-C6H4-4-N:N-1-C6H4-4-CC-1-C6H4-4-NO2)Cl(L2)2] (L2 = dppm (Ru1), dppe) (Ru2), trans-[Ru(CC-1-C6H4-4-N:N-1-C6H4-4-(E)-CH:CH-1-C6H4-4-NO2)Cl(dppe)2] (Ru3), and trans-[Ru(CC-1-C6H4-4-(E)-CH:CH-1-C6H2-2,6-Et2-4-N:N-1-C6H4-4-NO2)Cl(dppe)2] (Ru4) are reported, together with those of precursor alkynes. Their electrochem. properties were assessed by cyclic voltammetry (CV), linear optical and quadratic nonlinear optical (NLO) properties assayed by UV/Vis-NIR spectroscopy and hyper-Rayleigh scattering studies at 1064 nm, resp., and their linear optical properties in the formally RuIII state examined by UV/Vis-NIR spectroelectrochem. These data were compared to those of analogs with E-ene and yne linkages in place of the azo groups. Computational studies using time-dependent d. functional theory were undertaken on model compounds (Ru2′-Ru4′) to rationalize the optical behavior of the exptl. complexes.
ChemPlusChem published new progress about Crystal structure. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, COA of Formula: C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics