Ramadoss, Velayudham; Alonso-Castro, Angel J.; Campos-Xolalpa, Nimsi; Ortiz-Alvarado, Rafael; Yahuaca-Juarez, Berenice; Solorio-Alvarado, Cesar R. published the artcile< Total synthesis of kealiiquinone: the regio-controlled strategy for accessing its 1-methyl-4-arylbenzimidazolone core>, Application In Synthesis of 112-63-0, the main research area is kealiiquinone total synthesis.
A practical, concise and straightforward total synthesis of kealiiquinone, a naphtho[2,3-d]imidazole alkaloid obtained from the Micronesian marine sponge Leucetta sp. was accomplished. The squaric acid chem. to construct the 1,4-quinoid ring and the regioselective N-methylation through a benzo[c][1,2,5]selenadiazolium heterocycle are the key features in this report. The full details of the representative approaches involving the different attempted synthetic strategies are also presented. Finally a successful total synthesis of this complex secondary metabolite is described.
RSC Advances published new progress about Methylation, regioselective. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Application In Synthesis of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics