Qiu, Di; Zhang, Yan; Wang, Jianbo published the artcile< Direct synthesis of arylboronic pinacol esters from arylamines>, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is pinacol arylboronate aryloxaborolane preparation metal free arylamine borylation.
A metal-free synthetic method based on Sandmeyer-type transformation for preparation of arylboronic pinacol esters from easily available aromatic amines as starting materials was described. This novel transformation affords borylation products in good yields under mild reaction conditions. This strategy can be easily carried out in gram-scale, demonstrating the practical usefulness of the method. Moreover, the Sandmeyer-type transformation can be followed by Suzuki-Miyaura cross-coupling reaction without purification of the arylboronate products.
Organic Chemistry Frontiers published new progress about Aromatic amines Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics