Pellegrino, Anna L.; Mezzalira, Claudia; Mazzer, Francesco; Cadi Tazi, Lila; Caneschi, Andrea; Gatteschi, Dante; Fragala, Ignazio L.; Speghini, Adolfo; Sorace, Lorenzo; Malandrino, Graziella published the artcile< Multifunctional ""Dy(hfa)3•glyme"" adducts: Synthesis and magnetic/luminescent behaviour>, Synthetic Route of 112-63-0, the main research area is multifunctional dysprosium hexafluoroacetylacetone glyme adduct preparation magnetic behavior luminescence.
Dysprosium β-diketonate compounds have recently gained a lot of attention due to their intriguing multifunctional properties. In this paper, a series of “”Dy(hfa)3•glyme”” adducts have been prepared through a one-pot reaction, in dichloromethane, from dysprosium(III) acetate monohydrate, hexafluoroacetylacetone and glyme [Hhfa = 1,1,1,5,5,5-hexafluoroacetylacetone, glyme = bis-(2-methoxyethyl)ether, 2,5,8,11-tetraoxadodecane, 2,5,8,11,14-pentaoxapentadecane]. Based on the length of the polyether, various coordination frameworks have been obtained going from a mononuclear [Dy(hfa)3•diglyme] adduct, to a polymeric chain system for the [Dy(hfa)3•2H2O•triglyme], and an ionic structure for the [Dy(hfa)2•tetraglyme]+[Dy(hfa)4]-. The relationship between the coordination framework in the “”Dy(hfa)3•glyme”” series and the magnetic and luminescent properties has been deeply investigated.
Inorganica Chimica Acta published new progress about Luminescence. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Synthetic Route of 112-63-0.
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