Ma, Jun-An; Cahard, Dominique published the artcile< Screening of chiral catalysts for enantioselective electrophilic fluorination of β-keto esters>, Category: esters-buliding-blocks, the main research area is stereoselective fluorination keto ester chiral ligand.
A variety of oxygen- and nitrogen-containing chiral ligands in combination with various metals have been screened in the enantioselective electrophilic fluorination of tert.-Bu 2-oxocyclopentanecarboxylate. This study involved the use of readily available substrate, chiral ligands and electrophilic fluorinating agents. In particular, heterobimetallic Al-Li-BINOL complex led to enantiomerically enriched α-fluoro-β-keto ester in high yields and enantioselectivities ≤ 67% ee. A comparison with previously reported chiral ligands is provided.
Journal of Fluorine Chemistry published new progress about Chiral ligands Role: CAT (Catalyst Use), USES (Uses). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Category: esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics