Lockett-Walters, Bruce; Trujillo, Cristina; Twamley, Brendan; Connon, Stephen published the artcile< The base-catalysed Tamura cycloaddition reaction: calculation, mechanism, isolation of intermediates and asymmetric catalysis>, Synthetic Route of 112-63-0, the main research area is mechanism calculation base catalyzed Tamura cycloaddition.
A combined exptl. and computational investigation has revealed that the base-catalyzed Tamura cycloaddition between homophthalic anhydride and activated alkenes/alkynes – a reaction previously thought of as a Diels-Alder type process – proceeds via a stepwise mechanism involving conjugate addition and ring closure; which allowed the first catalytic asym. α-substitution reactions to be demonstrated with up to >99% ee.
Chemical Communications (Cambridge, United Kingdom) published new progress about Alkenes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Synthetic Route of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics