Haehsler, Martin; Mastalerz, Michael published the artcile< A Giant [8+12] Boronic Ester Cage with 48 Terminal Alkene Units in the Periphery for Postsynthetic Alkene Metathesis>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is giant cage alkene boronate cage self assembly preparation metathesis; boronic esters; covalent capture; organic cage; ring-closing metathesis; self-assembly.
Dynamic covalent chem. (DCC) is a powerful synthetic tool to construct large defined mols. in one step from rather simple precursors. The advantage of the intrinsic dynamics of the applied reversible reaction steps is a self-correction under the chosen conditions, to achieve high yields of the target compound To date, only a few examples are known, in which DCC was used to build up a mol. defined but larger product that was chem. transferred to a more stable congener in a second (irreversible) step. Here, we present a nanometer-sized [8+12] boronic ester cage containing 48 peripheral terminal alkene units which allows to put a hydrocarbon exoskeleton around the cage via alkene metathesis.
Chemistry – A European Journal published new progress about Boronic acids, esters Role: NAN (Nanomaterial), PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (cage compounds). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics