Yu, Xiaoye; Luebbesmeyer, Maximilian; Studer, Armido published an article in 2021. The article was titled 《Oligosilanes as Silyl Radical Precursors through Oxidative Si-Si Bond Cleavage Using Redox Catalysis》, and you may find the article in Angewandte Chemie, International Edition.Application of 2495-35-4 The information in the text is summarized as follows:
Oligosilanes are of great interest in the fields of organic photonics and electronics. In this communication, a highly efficient visible-light-mediated hydrosilylation of electron-deficient alkenes through cleavage of a trimethylsilyl-polysilanyl Si-Si bond is explored. These reactions smoothly occur on readily available organo(tristrimethylsilyl)silanes and other oligosilanes in the presence of an IrIII-based photo-redox catalyst under visible light irradiation Silyl radicals are generated through single electron oxidation of the oligosilane assisted by the solvent. The introduced method exhibits broad substrate scope and high functional group tolerance with respect to the organo(tristrimethylsilyl)silane and alkene components, enabling the construction of functionalized trisilanes. In addition, this catalytic system can be also applied to highly strained bicyclo[1.1.0]butanes as silyl radical acceptors. The results came from multiple reactions, including the reaction of Benzyl acrylate(cas: 2495-35-4Application of 2495-35-4)
Benzyl acrylate(cas: 2495-35-4) is a reagent that can be used in the preparation of 2-(Phosphonomethyl)pentanedioic Acid, a selective glutamate carboxypeptidase 2 (GCP-II) inhibitor. It can also be used in the preparation of high refractive index polyacrylates.Application of 2495-35-4
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