Safety of Benzyl acrylateIn 2020 ,《Sila- and Germacarboxylic Acids: Precursors for the Corresponding Silyl and Germyl Radicals》 was published in Angewandte Chemie, International Edition. The article was written by Xu, Ning-Xin; Li, Bi-Xiao; Wang, Chao; Uchiyama, Masanobu. The article contains the following contents:
Silicon-containing compounds are widely used as synthetic building blocks, functional materials, and bioactive reagents. In particular, silyl radicals are important intermediates for the synthesis and transformation of organosilicon compounds Herein, we describe the first protocol for the generation of silyl radicals by photoinduced decarboxylation of silacarboxylic acids, which can be easily prepared in high yield on a gram scale and are very stable to air and moisture. Irradiation of silacarboxylic acids with blue LEDs (455 nm) in the presence of a com. available photocatalyst releases silyl radicals, which can further react with various alkenes to give the corresponding silylated products in good-to-high yields with broad functional-group compatibility. This reaction proceeds in the presence of water, enabling efficient deuterosilylation of alkenes with D2O as the deuterium source. Germyl radicals were similarly obtained. After reading the article, we found that the author used Benzyl acrylate(cas: 2495-35-4Safety of Benzyl acrylate)
Benzyl acrylate(cas: 2495-35-4) is a reagent that can be used in the preparation of 2-(Phosphonomethyl)pentanedioic Acid, a selective glutamate carboxypeptidase 2 (GCP-II) inhibitor. It can also be used in the preparation of high refractive index polyacrylates.Safety of Benzyl acrylate
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