《Catalyst-Free Deaminative Functionalizations of Primary Amines by Photoinduced Single-Electron Transfer》 was written by Wu, Jingjing; Grant, Phillip S.; Li, Xiabing; Noble, Adam; Aggarwal, Varinder K.. Related Products of 2495-35-4This research focused ontriphenyl pyridinium tetrafluoroborate photochem single electron transfer deaminative reaction; Giese reactions; deamination; electron donor-acceptor complexes; photochemistry; radical reactions. The article conveys some information:
The use of pyridinium-activated primary amines as photoactive functional groups for deaminative generation of alkyl radicals under catalyst-free conditions was described. By taking advantage of the visible light absorptivity of electron donor-acceptor complexes between Katritzky pyridinium salts and either Hantzsch ester or Et3N, photoinduced single-electron transfer could be initiated in the absence of a photocatalyst. This general reactivity platform was applied to deaminative alkylation (Giese), allylation, vinylation, alkynylation, thioetherification and hydrodeamination reactions. The mild conditions were amenable to a diverse range of primary and secondary alkyl pyridiniums and demonstrate broad functional group tolerance. After reading the article, we found that the author used Benzyl acrylate(cas: 2495-35-4Related Products of 2495-35-4)
Benzyl acrylate(cas: 2495-35-4) is a reagent that can be used in the preparation of 2-(Phosphonomethyl)pentanedioic Acid, a selective glutamate carboxypeptidase 2 (GCP-II) inhibitor. It can also be used in the preparation of high refractive index polyacrylates.Related Products of 2495-35-4
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics