Widmer, Ulrich published the artcile< A convenient benzylation procedure for β-hydroxy esters>, Formula: C6H10O5, the main research area is benzylation hydroxy ester; ether benzyl.
Benzylation of β-hydroxy esters, containing primary and secondary alc. functions, with benzyl 2,2,2-trichloroacetamidate (I) gives the corresponding benzyl ethers in good yield. In the case of chiral substrates non racemization is observed Treatment of Me(CH2)10CH(OH)CH2CO2Me with I in the presence of a catalytic amount of F3CSO3H gave 79% Me(CH2)10CH(OCH2Ph)CH2CO2Me. Among the 5 other compounds similarly prepared were MeO2CCH2CH(OCH2Ph)CO2Me and PhCH2OCH2CH(Me)CO2Me.
Synthesis published new progress about Benzylation. 617-55-0 belongs to class esters-buliding-blocks, and the molecular formula is C6H10O5, Formula: C6H10O5.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics