Wang, Yaxin; Yang, Le; Liu, Shuai; Huang, Lixia; Liu, Zhong-Quan published the artcile< Surgical Cleavage of Unstrained C(sp3)-C(sp3) Bonds in General Alcohols for Heteroaryl C-H Alkylation and Acylation>, Synthetic Route of 112-63-0, the main research area is alc azaarene iodine promotor photochem Minisci reaction; alkyl azaarene preparation green chem regioselective.
A predictable and surgical cleavage of carbon-carbon bond in alcs. A wide range of 1°, 2° and 3° alcs. including sugars and steroids without ring strain or steric hindrance were all compatible with this system. Also it offered a green and practical strategy for generation of alkyl/acyl radicals using alcs. as the sources. Besides, the features of visible-light-initiation, catalyst and metal free, excellent selectivity and mild conditions made it valuable and attractive.
Advanced Synthesis & Catalysis published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Synthetic Route of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics