Postigo, Al published the artcile< Propagation chains in photocatalyzed radical nucleophilic substitutions of thiolates with perfluoroalkyl groups>, Synthetic Route of 4098-06-0, the main research area is thiol perfluorobutyl iodide perfluoroalkylation mecahnism quantum yield fluorescence quenching.
Quantum yields and radical chain lengths were investigated in photocatalyzed radical nucleophilic perfluorobutyl group substitution reactions of 2-mercaptothiolate anion under three different photocatalytic systems operating in reductive and quenching manners. Important propagation chain lengths were uncovered with photocatalysts under both scenarios, reductive and oxidative. The different overall quantum yields and chain lengths observed demonstrated the balance between the efficiency of the photoinitiation events, propagation and termination steps. Theor. calculations provide a better understanding and throw light into whether a closed or an open catalytic cycle is operating in photoinitiated perfluoroalkyl group-thiolate coupling reaction.
Chemical Physics Letters published new progress about Chemical chains. 4098-06-0 belongs to class esters-buliding-blocks, and the molecular formula is C12H16O7, Synthetic Route of 4098-06-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics