Girija, R.; Aruna, S. published the artcile< Oxidation of ortho-substituted benzyl alcohols by phenyliodoso acetate>, COA of Formula: C19H34O2, the main research area is oxidation ortho substituted benzyl alc phenyliodoso acetate kinetics.
Oxidation of benzyl alc. and some ortho-substituted benzyl alcs. by phenyliodoso acetate in t-Bu alc.:water medium (50:50) leads to the formation of corresponding benzaldehyde. The stoichiometry of the reaction is found to be 1:1. The reaction is first order each in substrate and oxidant concentrations This reaction is studied at four different temperature and the activation parameters are calculated Correlation anal. is carried out using Chartons Triparametric equation. The reaction is subjected to steric retardation by the ortho-substituents. The % of steric and resonance calculated A suitable mechanism has been proposed.
Asian Journal of Chemistry published new progress about Activation enthalpy. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, COA of Formula: C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics