Gautam, Prashant; Kathe, Prasad; Bhanage, Bhalchandra M. published the artcile< Pd/C catalyzed phenoxycarbonylation using N-formylsaccharin as a CO surrogate in propylene carbonate, a sustainable solvent>, Application In Synthesis of 112-63-0, the main research area is palladium catalyzed phenoxycarbonylation formylsaccharin carbon monoxide surrogate sustainable solvent; phenyl ester preparation green synthesis phenoxycarbonylation aryl iodide.
This work reports the first Pd/C catalyzed phenoxycarbonylation of aryl iodides using N-formylsaccharin as a CO surrogate. Advantageously, the reaction could be carried out in propylene carbonate, an environmentally benign and sustainable polar aprotic solvent under CO surrogacy. Using N-formylsaccharin as a CO surrogate allows the usage of cheaper and readily available phenols as the coupling partner. A range of Ph esters could be synthesized under mild, co-catalyst free, ligand free and additive free conditions, including multi-substituted novel Ph esters. The Pd/C catalyst could be recycled up to four times with only a slight loss in activity. The reaction could be scaled up to gram scale synthesis.
Green Chemistry published new progress about Aromatic esters Role: SPN (Synthetic Preparation), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Application In Synthesis of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics