Bhadra, Sukalyan; Dzik, Wojciech I.; Goossen, Lukas J. published the artcile< Synthesis of aryl ethers from aromatic carboxylic acids>, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is aryl ether preparation; aromatic carboxylate salt tetraalkyl orthosilicate trialkyl borate decarboxylative alkoxylation.
A silver/copper bimetallic catalyst system promotes the decarboxylative Chan-Evans-Lam alkoxylation of ortho-substituted aromatic carboxylate salts with tetraalkyl orthosilicates or trialkyl borates. Non-ortho-substituted carboxylates are alkoxylated via an ortho-C-H-alkoxylation with concomitant cleavage of the carboxylate directing group via protodecarboxylation. This way, meta-substituted carboxylates are converted into para-substituted alkoxyarenes and vice versa. The combined processes provide a convenient synthetic entry to the important class of aromatic ethers from widely available carboxylic acids.
Synthesis published new progress about Alkoxylation. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics