Pinet, Sandra; Liautard, Virginie; Debiais, Megane; Pucheault, Mathieu published the artcile< Radical Metal-Free Borylation of Aryl Iodides>, Quality Control of 112-63-0, the main research area is radical borylation aryl iodide steric hindrance; boronic ester preparation.
A simple metal-free borylation of aryl iodides mediated by a fluoride sp 2-sp 3diboron adduct is described. The reaction conditions are compatible with various functional groups. Electronic effects of substituents do not affect the borylation while steric hindrance does. The reaction proceeds via a radical mechanism in which pyridine serves to stabilize the boryl radicals, generated in situ.
Synthesis published new progress about Aryl iodides Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Quality Control of 112-63-0.
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